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For security purposes, Veracross is designed to only look for email addresses in the Email_1 field on the person record, so emails cannot be sent to multiple emails stored on a single person record.
In order to send business and personal emails to separate email accounts for the same person, you can create separate person records, one for their faculty role and a second for their parent role associating the school and personal email addresses with each. It is important to communicate with your staff that this is an intentional duplicate person so they aren't accidentally merged.